CHEMICAL EFFECTS OF ELECTRIC CURRENT
CHEMICAL EFFECTS OF ELECTRIC CURRENT — Study Notes
NCERT-aligned · 7 notes · 3 shown free
Introduction
ExplanationIntroduction
Electric current is a flow of electric charge through a conductor. When electric current passes through certain substances, it can produce chemical changes. This phenomenon is known as the chemical effect of electric current. In this chapter, we will explore how electric current can cause chemical reactions, which substances show this effect, and the practical applications of this phenomenon. The chemical effect of electric current is the basis for many important industrial and household processes, such as electroplating, electrolysis, and purification of metals. The chapter begins by revisiting the concept of electric current and then moves on to experiments demonstrating chemical effects, followed by detailed explanations of electrolysis, its applications, and related concepts.
- Electric current is the flow of electric charge through a conductor.
- Chemical effect of electric current refers to chemical changes caused by electric current.
- Certain substances like liquids containing ions show chemical effects when current passes through them.
- This effect is used in electroplating, electrolysis, and purification of metals.
- Understanding this effect helps in practical applications in industries and daily life.
- 📌 Electric current: Flow of electric charge through a conductor.
- 📌 Chemical effect of electric current: Chemical changes produced by electric current.
Chemical Effects of Electric Current
ExplanationChemical Effects of Electric Current
When an electric current passes through a conducting liquid, chemical changes occur in the liquid and on the electrodes. This is because the conducting liquid contains ions, which move towards the electrodes of opposite charge. Positive ions (cations) move towards the cathode (negative electrode), and negative ions (anions) move towards the anode (positive electrode). At the electrodes, these ions either gain or lose electrons, resulting in chemical reactions such as deposition of metals or liberation of gases. This process is called electrolysis. The chemical effect of electric current is observed in electrolytes, which are substances that conduct electricity in molten or aqueous states due to the presence of ions. For example, when electric current is passed through molten lead bromide, lead metal is deposited at the cathode and bromine gas is released at the anode. This shows that electric current can cause chemical decomposition of compounds into their elements.
- Electric current causes chemical changes in conducting liquids called electrolytes.
- Ions in the electrolyte move towards electrodes of opposite charge.
- Cations move to cathode; anions move to anode.
- Chemical reactions at electrodes cause deposition or liberation of elements.
- Electrolysis is the process of chemical decomposition by electric current.
- Example: Molten lead bromide decomposes into lead and bromine on electrolysis.
- 📌 Electrolyte: Substance that conducts electricity due to presence of ions.
- 📌 Electrolysis: Chemical decomposition caused by electric current.
- 📌 Cations: Positively charged ions.
Electroplating
ExplanationElectroplating
Electroplating is a process that uses the chemical effect of electric current to coat the surface of a metal object with a thin layer of another metal. This is done to improve the appearance of the object, prevent corrosion, or reduce friction. In el
Practice Questions — CHEMICAL EFFECTS OF ELECTRIC CURRENT
Includes NCERT exercise questions with answers
Q1.1. Fill in the blanks. (a) Most liquids that conduct electricity are solutions of __________, __________ and __________. (b) The passage of an electric current through a solution causes __________ effects. (c) If you pass current through copper sulphate solution, copper gets deposited on the plate connected to the __________ terminal of the battery. (d) The process of depositing a layer of any desired metal on another material by means of electricity is called __________.
Answer:
(a) Most liquids that conduct electricity are solutions of acids, bases and salts. (b) The passage of an electric current through a solution causes chemical effects. (c) If you pass current through copper sulphate solution, copper gets deposited on the plate connected to the negative terminal of the battery. (d) The process of depositing a layer of any desired metal on another material by means of electricity is called electroplating.
Explanation:
Liquids that conduct electricity typically contain ions, which are present in solutions of acids, bases, and salts. When electric current passes through such solutions, chemical changes occur (chemical effects). In copper sulphate solution electrolysis, copper ions move towards the cathode (negative terminal) and get deposited there. Electroplating is the process of depositing a metal layer on another material using electric current.
Q2.2. When the free ends of a tester are dipped into a solution, the magnetic needle shows deflection. Can you explain the reason?
Answer:
The magnetic needle shows deflection because the solution conducts electricity, allowing current to flow through the circuit. The current produces a magnetic field around the wire, which causes the magnetic needle to deflect.
Explanation:
When the tester's free ends are dipped into a conducting solution, ions in the solution carry electric current. The current flowing through the wire creates a magnetic field, which interacts with the magnetic needle causing it to deflect. This indicates the solution is a conductor of electricity.
Q3.3. Name three liquids, which when tested in the manner shown in Fig.11.9, may cause the magnetic needle to deflect.
Answer:
Three liquids that may cause the magnetic needle to deflect are: 1. Salt water (solution of common salt in water) 2. Lemon juice (acidic solution) 3. Vinegar (acetic acid solution)
Explanation:
These liquids contain ions which can conduct electricity. When the tester is dipped into these liquids, current flows through the circuit, producing a magnetic field that deflects the magnetic needle as shown in Fig. 11.9.
Q4.4. The bulb does not glow in the setup shown in Fig.11.10. List the possible reasons. Explain your answer.
Answer:
Possible reasons why the bulb does not glow: 1. The liquid in the container may not be conducting electricity (e.g., pure water). 2. There may be a loose connection or break in the circuit. 3. The bulb may be fused or faulty. 4. The battery may be dead or not connected properly. Explanation: For the bulb to glow, the circuit must be complete and the liquid must conduct electricity to allow current flow. If any of these conditions fail, the bulb will not glow.
Explanation:
The bulb glows only if current flows through the circuit. If the liquid is non-conducting, no current flows. Similarly, loose connections or faulty components prevent current flow, causing the bulb to remain off.
Q5.5. A tester is used to check the conduction of electricity through two liquids, labelled A and B. It is found that the bulb of the tester glows brightly for liquid A while it glows very dimly for liquid B. You would conclude that (i) liquid A is a better conductor than liquid B. (ii) liquid B is a better conductor than liquid A. (iii) both liquids are equally conducting. (iv) conducting properties of liquid cannot be compared in this manner.
Answer:
Option (i) liquid A is a better conductor than liquid B. Explanation: The brightness of the bulb depends on the amount of current flowing through the circuit. A brighter bulb indicates higher current, which means liquid A conducts electricity better than liquid B.
Explanation:
Since the bulb glows brightly with liquid A and dimly with liquid B, it shows that liquid A allows more current to pass through, indicating better conductivity.
Q6.6. Does pure water conduct electricity? If not, what can we do to make it conducting?
Answer:
Pure water does not conduct electricity because it lacks free ions. To make it conducting, we can add a small amount of an electrolyte such as salt, acid, or base to produce ions that carry electric current.
Explanation:
Pure water is a poor conductor as it contains very few ions. Adding substances like salt dissociates into ions, enabling the solution to conduct electricity.
Q7.7. In case of a fire, before the firemen use the water hoses, they shut off the main electrical supply for the area. Explain why they do this.
Answer:
Firemen shut off the main electrical supply before using water hoses because water conducts electricity. If the electrical supply is not turned off, water can conduct electricity and cause electric shocks, posing danger to the firemen.
Explanation:
Water is a conductor of electricity when it contains impurities. Using water near live electrical circuits can cause electric shocks. To ensure safety, electrical supply is switched off before water is used.
Q8.8. A child staying in a coastal region tests the drinking water and also the seawater with his tester. He finds that the compass needle deflects more in the case of seawater. Can you explain the reason?
Answer:
Seawater contains more dissolved salts (ions) than drinking water. These ions increase the conductivity of seawater, allowing more current to flow, which causes greater deflection of the compass needle.
Explanation:
The presence of dissolved salts in seawater provides more charge carriers (ions), resulting in better conduction of electricity compared to drinking water, hence the larger deflection.
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